One of the things people confuse with Premium gas or high octane gas is the words used to sell it. 80 octane gas is better than 100 octane gas when it comes to being volital. If you replaced the word premium with the word junk, it would make more sense. The higher the octane the more junk it has in it to keep it from exploding. That junk gets on your valve stems and spark plugs and will eventually causes problems. It's the junk that stops up catalitic converters. Junk, Junk, Junk.
You need this junk to keep a high compression engine from exploding the gas too soon. I would suggest to anyone with a high compression engine to try to use the minimum amount of junk required to keep his engine from pre-detination ( pinging ). It's junk guys, pure and simple. If they could have got dirt to mix with the gas they'd have used dirt to make super dupper high octane premium racing fuel. Jim PS. Hottarod, to make a pre-determination on what octane you'll need to run in your car you need to know the DCR (dynamic compression ratio). Standard compression ration won't factor in your valve opening and closing. You need this to determine what octane will be required. I've seen a couple of graphs on the web that depict octane rating vs. DCR. You need to figure that first. If you are just bound and determined you want to use 100LL Avgas go get some and use it straight up. Cars will run just fine with more octane than what's needed, just not as long. I've used thousands of gallons of 100LL and I've overhauled my engine at a cost of $20,000 dollars, had broken valves, cleaned spark plugs and done God knows how many leakdown tests twice because of pieces of junk caught between the valve and seat. You can believe me or some guy that knew a guy that had a brother that used 100LL and just loved it and didn't cause any problems whatsoever.